{μ-2-[(Benzothiazol-2-yl-2κN)hydrazonomethyl-2κN]-6-methoxyphenolato-1:2κ3 O 1,O 6:O 1}{2-[(benzothiazol-2-yl-1κN)hydrazonomethyl-1κN]-6-methoxyphenolato-1κO 1}(methanol-2κO)(nitrato-2κO)dicopper(II) nitrate
نویسندگان
چکیده
The title complex, [Cu(2)(C(15)H(12)N(3)O(2)S)(2)(NO(3))(CH(3)OH)]NO(3), has two Cu(II) centres coordinated by two deprotonated 2-[(benzothia-zol-2-yl)hydrazonometh-yl]-6-methoxy-phenol ligands, a methanol mol-ecule and a nitrate ion. Both Cu(II) centres are penta-coordinated in a distorted square-pyramidal fashion. The crystal structure is stabilized by N-H⋯O and O-H⋯O hydrogen bonds.
منابع مشابه
Crystal structures of bis- and hexakis[(6,6′-dihydroxybipyridine)copper(II)] nitrate coordination complexes
Two multinuclear complexes synthesized from Cu(NO3)2 and 6,6'-di-hydroxy-bipyridine (dhbp) exhibit bridging nitrate and hydroxide ligands. The dinuclear complex (6,6'-di-hydroxy-bipyridine-2κ(2) N,N')[μ-6-(6-hy-droxy-pyridin-2-yl)pyridin-2-olato-1:2κ(3) N,N':O (2)](μ-hydroxido-1:2κ(2) O:O')(μ-nitrato-1:2κ(2) O:O')(nitrato-1κO)dicopper(II), [Cu2(C10H7N2O2)(OH)(NO3)2(C10H8N2O2)] or [Cu(6-OH-6'-O-...
متن کامل{μ-2-[(3-Amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1:2κ5 O 1,O 6:N,N′,O 1}{2-[(3-amino-2,2-dimethylpropyl)iminomethyl]-6-methoxyphenolato-1κ3 N,N′,O 1}-μ-azido-1:2κ2 N:N-azido-2κN-methanol-2κO-dinickel(II)
Two distinct coordination geometries are found in the binuclear title complex, [Ni(2)(C(13)H(19)N(2)O(2))(2)(N(3))(2)(CH(3)OH)], as one Schiff base ligand is penta-dentate, coordinating via the anti-cipated oxide O, imine N and amine N atoms (as for the second, tridentate, ligand) but the oxide O is bridging and coordination also occurs through the meth-oxy O atom. The Ni(II) atoms are linked b...
متن کاملcatena-Poly[bis(μ4-adipato-1:2:1′:2′κ4 O 1:O 1′:O 4:O 4′)bis(N,N-dimethylformamide)-1κO,2κO-dicopper(II)]
In the title polymeric complex, [Cu(2)(C(6)H(8)O(4))(2)(C(3)H(7)NO)(2)](n), the carboxyl-ate groups of the approximately U-shaped adipate dianion each bridge a pair of inversion-related, DMF-coordinated copper(II) atoms, generating a ribbon motif that runs along the b axis. The geometry of the copper(II) atom is distorted square-pyramidal; the apical site is occupied by the O atom of the DMF mo...
متن کاملTwo coordination modes of CuII in a binuclear complex with N-(pyridin-2-ylcarbonyl)pyridine-2-carboxamidate ligands
In the title dinuclear complex, (acetonitrile-1κN)[μ-N-(pyri-din-2-ylcarbonyl)pyridine-2-carboxamidato-1:2κ(5)N,N',N'':O,O'][N-(pyridin-2-ylcarbonyl)pyridine-2-carboxamidato-2κ(3)N,N',N'']bis(trifluoromethanesulfonato-1κO)dicopper(II), [Cu(2)(C(12)H(8)N(3)O(2))(2)(CF(3)O(3)S)(2)(CH(3)CN)], one of the Cu(II) ions is five-coordinated in a distorted square-pyramidal N(3)O(2) environment provided b...
متن کاملcatena-Poly[[(2-{1-[2-(2-aminoethylamino)ethylimino]ethyl}-5-methoxyphenolato-κ4 N,N′,N′′,O)copper(II)]-μ-nitrato-κ2 O:O′]
In the title compound, [Cu(C(13)H(20)N(3)O(2))(NO(3))](n), the Cu(II) atom is chelated by the Schiff base ligand via three N atoms and one O atom lying in an approximate square plane (r.m.s. deviation = 0.04 Å). The complex mol-ecules are linked into a polymeric chain by bridging nitrate anions, forming axial Cu-O bonds of 2.535 (6) and 2.676 (7) Å, completing a distorted octa-hedral coordinati...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009